Often, when I open for the first time Blender and try to open the VFB window (V-Ray → V-Ray VFB), it doesn’t open. It’s only after starting a render with the render button that opening the VFB window is enabled.
Does this only happen only in the time shortly after starting Blender or in general the VFB doesn’t want to open? V-Ray usually needs some time to initialize during which many of our commands don’t work. This is even worse on MacOS the first time you run Blender with V-Ray installed and we have an issue logged to improve this.