Your first image has Color Balance 4500K. 4500K is warm color that is substracted from image so it will be (6500K -4500K=2000K) cooler.
Your second images has Color Balance of 8000K. 8000K is light blueish color that is substracted, it will be 2000K warmer.
It works identically to how it is in physical camera (and real-world camera and photo RAW editors).
At first sight I agree, it might seem counterintuitive. But you have to consider the logic where it came from in photography.
It helps you easily balance against known black-body temperatures, so if light-bulb lit set of 2800K, you want to achieve correct white, you set the white ‘balance’ to 2800K.
If common daylight temperature is 5000-5500K +/- in Central Europe midday, you will set your white-balance to roughly this, and you don’t even have to search for any white object in your scene, or bring grey-card along. You don’t need to do any math.