The Enscape crashed when first launched in rhino. Someone said it was because of the win10 OS? And the material applied in rhinoceros changed to something else when rendered in enscape. 
In order to show your rhino materials in Enscape, you have to change the material type to Enscape.
Follow this link: https://enscape3d.com/community/blog/knowledgebase/materials-in-rhino/
I’m sorry to hear about that! It shouldn’t be caused by Windows 10 itself since that version if officially supported by Enscape; to get behind this problem as fast as possible please send in a report here, briefly detailing your issue in the submission thread. Thank you in advance.
Also, the materials may indeed look a bit different since not every material parameter of Rhino itself is supported, but that is why we provide a dedicated Rhino material editor which you can feel free to use, we definitely recommend it!
Finally, a warm welcome to our forum! 