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Applying materials to a polysurface is not yet supported in Rhino currently so we are not able to implement it. However, as a workaround, you can prepare the desired V-Ray materials, select the surfaces by Ctrl+Shift+clicking on them, and then from the Rhino menu > Properties > Materials, select the V-Ray materials you want applied for each face. See attached gif for a better visual explanation: http://ftp.chaosgroup.com/support/sc...8_16-24-05.gif
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